Benzyl Chloride
- Product Name: Benzyl Chloride
- Chemical Name (IUPAC): (Chloromethyl)benzene
- CAS No.: 100-44-7
- Chemical Formula: C7H7Cl
- Form/Physical State: Liquid
- Factroy Site: Zouping City, Binzhou City, Shandong Province, China
- Price Inquiry: sales7@bouling-chem.com
- Manufacturer: Xiwang Pharmaceutical
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|
HS Code |
261185 |
| Chemicalname | Benzyl Chloride |
| Casnumber | 100-44-7 |
| Molecularformula | C7H7Cl |
| Molecularweight | 126.59 g/mol |
| Appearance | Colorless to slightly yellow liquid |
| Odor | Pungent, irritating odor |
| Boilingpoint | 179 °C (354 °F) |
| Meltingpoint | -39 °C (-38 °F) |
| Density | 1.10 g/cm³ at 20 °C |
| Solubilityinwater | Immiscible |
| Vaporpressure | 1.3 mmHg at 25 °C |
| Flashpoint | 65 °C (closed cup) |
| Refractiveindex | 1.538 at 20 °C |
| Autoignitiontemperature | 570 °C (1058 °F) |
| Unnumber | 1738 |
As an accredited Benzyl Chloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Benzyl Chloride is packaged in a sealed 500 mL amber glass bottle with a tight screw cap and clearly labeled hazard warnings. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL) for Benzyl Chloride: Typically 80-100 drums (net 16-20MT), securely packed, compliant with IMDG hazardous regulations. |
| Shipping | Benzyl Chloride must be shipped as a hazardous material, classified as UN1738, Class 6.1 (toxic substance). It should be packaged in leak-proof containers, clearly labeled, and transported in accordance with local, national, and international regulations. Avoid exposure to heat, moisture, and incompatible substances during transit. Use proper personal protective equipment when handling. |
| Storage | Benzyl Chloride should be stored in a cool, dry, well-ventilated area, away from heat, open flames, and direct sunlight. Keep the container tightly closed and clearly labeled. Store separately from oxidizers, strong bases, and strong acids. Use corrosion-resistant containers or packaging. Ensure safety equipment and spill containment measures are available in the storage area to handle accidental releases. |
| Shelf Life | Benzyl chloride typically has a shelf life of 2 years when stored tightly sealed, away from light, moisture, and incompatible substances. |
Competitive Benzyl Chloride prices that fit your budget—flexible terms and customized quotes for every order.
For samples, pricing, or more information, please contact us at +8615371019725 or mail to sales7@bouling-chem.com.
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Tel: +8615371019725
Email: sales7@bouling-chem.com
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- Benzyl Chloride is manufactured under an ISO 9001 quality system and complies with relevant regulatory requirements.
- COA, SDS/MSDS, and related certificates are available upon request. For certificate requests or inquiries, contact: sales7@bouling-chem.com.
Benzyl Chloride: Direct from Our Production Facility
Understanding Benzyl Chloride from a Chemical Manufacturer’s Perspective
Benzyl chloride is a cornerstone compound in chemical synthesis, serving a broad range of industries. After decades of working with aromatic compounds, our facility has seen how this chlorinated toluene derivative shapes key processes for manufacturers who rely on a rich supply chain. Chemists know it for its pungent odor and the unmistakable way it reacts with nucleophiles. Every batch produced here goes directly from our reactors to bulk containers for shipment, eliminating unnecessary steps and keeping consistency under tight control.
Production and Purity: Everyday Realities
Producing benzyl chloride takes both precision and experience. We chlorinate toluene in a controlled environment, applying the optimal temperature and UV exposure as dictated by reaction kinetics. This method creates a clear, slightly yellow liquid with a purity that commercial users demand. To give a sense of scale: we routinely meet a minimum purity of 99.0%, and we spot-check for known impurities like benzyl alcohol and benzaldehyde. These details make a difference, especially when the end customer synthesizes pharmaceuticals or specialty polymers. Even small variations in trace content can alter downstream yields or color, which is why we monitor specifications closely before dispatch.
Typical Model and Specification Expectations
Most buyers request either standard or high-purity benzyl chloride, packed by the drum or isotank. Common packaging formats include 250-kg drums or larger bulk containers for repeat users. Density stays close to 1.1 g/cm³ at 20°C, and we keep water content well below 0.05%. Our technical team checks for acid and free chlorine residue, signing off each batch only once it clears all specification points. In effect, it is never just about volume; getting those finer details right keeps customer equipment free of corrosion or residue. Over the years, we've seen how industrial users—from dye intermediates to flavor and fragrance plants—shape their requests around these numbers.
A Closer Look at Usage: Real-World Experience
Benzyl chloride rarely ends up in a finished product on a store shelf. Most of its value comes from forming intermediates through nucleophilic substitution. Our longstanding partners in the manufacturing of benzyl alcohols, benzyl ethers, and benzylic quaternary ammonium salts buy regularly for these processes. For resins and plastics, it acts as a crosslinker, imparting rigidity and thermal properties to end products. Our crew has also shipped to companies making photographic chemicals, pesticides, and specialty surfactants. Each use requires the same reliability: when chemists plan a batch reaction, they demand reactivity without surprise side reactions.
The main application by volume has long been the synthesis of benzyl alcohol by hydrolysis, followed by the formation of phenylacetic acid through the cyanide route. Fragrance houses value benzyl chloride for its role as a building block. The projection is that fine chemicals and active pharmaceutical ingredient industries will continue to see growing demand for this compound, given the ongoing diversification of custom synthesis. These downstream uses place a practical requirement on us: providing timely technical support, understanding transport regulations, and saving turnaround times when production schedules tighten.
Why Purity Matters: What We Have Learned
During various scale-ups, trace contaminants have shown an outsized effect on subsequent chemical processes. For instance, the conversion to benzyl alcohol via hydrolysis can falter if the original batch of benzyl chloride contains elevated benzaldehyde or other oxidized by-products. Through experience, we've found that precise control of temperature and stoichiometry at the chlorination stage can significantly limit these side products. We back up these findings with rigorous gas chromatography checks and select infrared techniques, aiming to deliver benzyl chloride that supports high-yielding, low-waste reactions for our customers.
Our engineers have collaborated closely with process owners in the pharmaceutical sector, who confirm time and again that upholding tight impurity thresholds reduces unexpected color formation and resin fouling downstream. In synthetic polymer plants, even small upticks in water or residual acidity can trigger batch rejections with expensive repercussions. Engineering improvements—named tube-in-shell heat exchangers and custom UV lamp arrays—were introduced in direct response to field feedback from end users who experienced downtime.
Safe Handling and Transport: A Manufacturer’s Viewpoint
Working every day with benzyl chloride sharpens our appreciation for the need to manage risks, both inside the plant and along the transport route. The compound aggressively irritates skin and mucous membranes; inhalation brings regulatory scrutiny and strict air monitoring. That’s the reality crew members navigate. We maintain storerooms fitted with scrubbers, and we train every handler in leak response. Loaded drums and tanks move through our dock with all DOT and ADR-compliant labels, soon bound for customers’ storage tanks with their own breathing apparatus and mitigation protocols ready.
Transport regulations have toughened over the years, especially in export regimes. We address these shifts by assigning compliance specialists who audit each shipment for material safety data, labeling accuracy, and secondary containment. As supply chains stretch worldwide, direct coordination with freight forwarders cuts down on mishandling. It’s not rare for clients to call back for advice on venting, fitting selection, or staff instruction. We share operational best practices instead of leaving buyers unsupported. This level of engagement, learned through decades of loading hazardous shipments, protects everyone in the chain.
Comparing Benzyl Chloride with Related Aromatic Halides
Customers sometimes weigh benzyl chloride against toluene derivatives like benzyl bromide, or even chlorinated solvents such as chlorobenzene. Every product brings its own reactivity, cost, and hazard profile. From technical ground truth, benzyl chloride occupies a middle ground: less active than benzyl bromide yet more selective than monochlorotoluenes. The greater availability of toluene as a base feedstock for chlorination enables pricing predictability at scale.
In our operations, we see that substituting with benzyl bromide increases cost pressures and complicates logistics due to the stricter handling profile of brominated organics. Chlorobenzene would behave very differently in electrophilic reaction systems, missing the unique benzylic reactivity that underpins so many substitution or condensation protocols found in the benzyl chloride value chain. Regular discussions with synthetic organic chemists reinforce the distinct role benzyl chloride plays—its reactivity suits alkylation and etherification schemes not covered by direct analogues.
Continuous Improvement in Process Efficiency and Emission Control
Keeping pace with environmental regulations and efficiency improvements shapes our daily routines. Any aromatic chlorination carries the burden of managing HCl emissions and minimizing side-product generation. Our technical staff works on routinely upgrading reactor seals, introducing catalytic off-gas treatment, and closing process loops where possible. These measures don’t just serve regulatory compliance—they measurably improve solvent recovery rates, reduce effluent bills, and increase thermal economy on site.
We made it standard practice to route off-gases from the chlorination process into water scrubbers, trapping hydrochloric acid and preventing workplace exposure. Solid catalysts designed for selectivity keep unwanted dichlorotoluenes at bay, improving the yield of benzyl chloride. These refinements, born out of the plant floor rather than a theoretical design office, have kept our operation resilient and competitive. Year by year, we share these technical outcomes with procurement managers and research partners so they directly see the return on process reliability and green chemistry claims.
Handling Customer Challenges and Custom Requests
Conversation with our customers consistently highlights new requirements—stricter impurity limits, batch-specific certifications, alternate packaging adapted to unique plant intake systems. One pharmaceutical group requested material below 0.02% benzyl alcohol; another wanted direct line-filling into ISO tanks under nitrogen to prevent degradation in transit. Meeting these asks means going beyond standard batch release silos. Our lab team schedules additional spot analyses and documents custom handling as part of the official batch record.
Fulfilling urgent or unusual requests isn’t simply a matter of changing labels. Installing dedicated transfer lines with inert gas purging, modifying warehouse workflows, and documenting serial numbers for batch traceability are labor-intensive steps we commit to for strategic partnerships. These adjustments came from actual project experiences, where feedback from site engineers led us to revise standard operating procedures in ways that benefited all buyers. The result: stronger relationships, with both sides learning from each batch cycle and adapting processes accordingly.
Worker Safety and Community Engagement
Behind every drum and tank shipped, there is a crew of operators who handle benzyl chloride day in and out. Our company’s oldest foreman points out that workplace practices cannot stand still. The safety gear issued five years ago doesn't always match today’s best standards. Respirator models change, and so do protocols for managing spills or vapors. Before anyone enters the chlorination suite, they train on new sensing equipment, emergency scrubbers, and scenario planning for accidental releases.
Practical lessons from the plant feed into our safety case updates, and regular engagement with local authorities ensures that emergency planning happens on both sides of the site fence. We invite community feedback on noise, odor, and transport routes, acting on complaints with prompt adjustments. Over time, transparency about our operations—good news and challenges alike—improves neighbor relationships. As a mid-scale manufacturer in a regulated zone, we see that open channels build trust and keep the workforce safe. The continual aim is to show yearly improvements in accident frequency rates, emergency response times, and emission tracking, drawing directly from plant data.
Supply Chain and Untangling Disruptions
Benzyl chloride seldom travels alone. Bulk orders for this product frequently arrive alongside stacks of sodium hydroxide, toluene, and other related feedstocks. In periods of logistics congestion, direct communication with supplier and customer facilities bridges delay gaps. We avoid multi-tiered intermediaries, prioritizing clear shipment tracking and accurate delivery forecasts. By owning the production pipeline end-to-end, accountability stays clear. Problems caused by port delays, weather, or regulatory holds get relayed right to customers with a plan for workarounds.
Raw material quality remains variable country-to-country. Running on-the-ground QC in the supply chain helps dodge incoming contaminants before they ever reach the chlorinators. This reduces the risk of batch rejection downstream. An ongoing effort to negotiate consistent toluene grades and verify their origin has paid off in lower impurity loads and improved reliability of finished benzyl chloride. Project managers from client sites routinely audit our plant, inspecting not just end product, but incoming drum storage, process logs, and scrubbing efficiency. We encourage these deep dives as they keep both sides focused on process transparency and mutual learning.
Regulatory Awareness and Documentation: Keeping Operations Smooth
Across the years, regulation of benzyl chloride has grown more stringent. The compound appears regularly on controlled substance lists in many jurisdictions, due to its use in chemical synthesis. Our compliance team closely tracks changing laws, from domestic environmental requirements to global conventions. Export paperwork involves declarations, cargo manifest updates, and shipment authorizations that match the specific stringency in the destination country.
During audits, we expect requests for detailed documentation – certificates of origin, batch-specific certificates of analysis, statements of compliance. Years of maintaining up-to-date operations paperwork mean that we rarely scramble during scheduled checks. We routinely provide original analysis sheets with every order, and we honor requests for enhanced traceability when clients operate under regulated conditions. Investing in compliance capability up front minimizes interruptions, letting manufacturing and logistics run without gaps.
Research and Collaboration with End Users
Not all innovation in the benzyl chloride space starts with research labs. Many of the practical process changes in our plant emerge from ongoing dialogue with bulk customers trying new reactions or routes. Insights from polymer chemists who saw yield drops caused by trace side-products led to sampling regimens that directly reduced off-spec claims. Field evidence from small bromide traces in benzyl chloride shipments off a certain toluene source led to raw material vetting and a change in preferred upstream partners.
Long-term relationships create the trust needed for shared pilot runs. Several clients have invited our engineers onsite to observe continuous-flow reactions using benzyl chloride, troubleshooting heat control and dispersion issues live. We share our own plant analytics—IR, GC, and Karl Fischer titrations—while receiving real-world feedback to inform our own process tweaks. It’s a virtuous cycle: upstream process knowledge sharpens downstream product performance, and input from end users in turn leads to further process upgrades.
Market Shifts and Price Stability
Benzyl chloride’s price reflects fluctuations in toluene and chlorine feedstock costs, energy inputs, labor, and regulatory overhead. Several times, market uncertainty from geopolitical events caused ripple effects through inventory and forward contract pricing. Our scale gives us stability, but price spikes carry real risks for buyers without established supplier relationships. Forecasting future demand takes close coordination with users. If a downstream polymer plant doubles output, our procurement must match the increased need for raw materials promptly.
To manage market volatility, we enter into offtake agreements, forward buy essential feedstocks, and maintain buffer inventories to bridge transportation bottlenecks. These choices, drawn from seasoned forecasting, keep production lines humming without costly stops. In periods of surplus, flexibility around packaging and dispatch allows us to shift product between different client segments, reducing the risk of holding excessive stocks.
Sustainability Initiatives and Future Directions
In the last decade, customer interest has shifted toward greener chemical processes and reduced-waste manufacturing. Benzyl chloride producers face the challenge of managing both the inherent risks of halogenated production and the shifting environmental benchmarks of clients. Our current site makes active use of closed-loop cooling, solvent recycling, and energy recovery on exothermic stages. These changes have reduced both emissions and overall production cost compared to older open-cycle designs we retired years ago.
We track the emerging science in catalytic chlorination and greener alternative routes. Investments in research and in-field pilot programs—both on our site and in collaboration with industry partners—show promise for further reducing waste and off-gas burdens. As regulations tighten and public expectations increase, commitment to continuous improvement remains key. Working with—and learning from—users focused on green chemistry makes our progress tangible, not just a talking point in a brochure.
In It for the Long Haul
Benzyl chloride production isn’t glamorous, but the compound continues to support a wide swath of industrial chemistry. The technical lessons gathered on the floor—purity control, emission reduction, collaboration with users—shape both production and service. Every tanker sent to a partner plant reflects years of practical learning, ongoing safety work, and close attention to regulatory realities. Direct manufacturing connection offers the dependability customers need, especially in a chemical segment where both volatility and regulatory scrutiny remain high.
Each process adjustment, safety improvement, and customer consultation reinforces the importance of experience. This stability allows manufacturers and buyers alike to plan, adapt, and keep projects moving forward, even as regulations evolve and supply chains change. Through decades of working closely with customers, suppliers, and our own plant floor, we continue striving to deliver benzyl chloride that meets high technical standards and supports the growth of synthesis capabilities worldwide.