Product Name: Crystalline Fructose
Chemical Name: D-Fructose
CAS Number: 57-48-7
Synonyms: Levulose, Fruit Sugar
Intended Use: Food ingredient, sweetener
Manufacturer Contact: Full name, address, phone, emergency contact
Recommended Restrictions: Not recommended for use except as food ingredient or approved industrial applications
Classification: Not classified as hazardous under GHS standards for health or environment
Potential Health Effects: Dust inhalation may cause mild irritation of respiratory tract. Contact may cause minor eye and skin irritation. No chronic health effects expected from typical use
Label Elements: No pictogram required
Signal Word: None
Hazard Statements: None assigned
Precautionary Statements: Avoid breathing dust. Wash hands thoroughly after handling. Avoid contact with eyes
Chemical Identity: D-Fructose
Concentration: 99% or higher
Impurities/Additives: Trace amounts of water and plant-derived substances, not considered hazardous
Inhalation: Move person to fresh air. If symptoms persist, seek medical advice
Skin Contact: Wash area with mild soap and water. Remove contaminated clothing
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do
Ingestion: Rinse mouth with water. Drink plenty of water. Seek medical attention for large quantities
Major Symptoms: Dust may cause mild, temporary irritation to eyes or throat
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: None known for this product
Hazardous Combustion Products: Carbon monoxide and dioxide, possibly irritating fumes
Special Protective Equipment: Firefighters should use self-contained breathing apparatus
Specific Hazards: Fine dust can form explosive mixtures with air when suspended. Control dust accumulation
Personal Precautions: Use personal protective equipment as described in exposure controls. Avoid dust formation. Avoid contact with eyes
Environmental Precautions: Prevent spills from entering drains or waterways, though no major ecological risk
Cleanup Methods: Transfer large spills into clean, dry containers for recovery or disposal. Sweep up small spills, flush area with water to prevent dust
Disposal: Follow local regulations for disposal
Handling: Minimize dust generation. Use adequate ventilation. Handle in accordance with food safety guidelines
Hygiene Measures: Wash hands after handling. Do not eat, drink, or smoke while handling
Storage: Store in tightly sealed container. Keep in a cool, dry, well-ventilated area away from strong odors and chemicals. Protect from heat and moisture. Recommended storage temperature below 30°C. Avoid direct sunlight
Occupational Exposure Limits: Not established for fructose. Use general particulate exposure limits (e.g., OSHA PEL for nuisance dust – 15 mg/m³ total dust)
Engineering Controls: Use local exhaust ventilation to minimize airborne dust
Respiratory Protection: Use dust mask or NIOSH-approved respirator if dust levels exceed limits
Eye Protection: Safety glasses with side shields recommended
Skin Protection: Wear protective gloves for repeated or prolonged contact
Other Protective Equipment: Standard laboratory coats or work clothing. Eyewash station should be available in handling areas
Appearance: White, crystalline powder
Odor: Odorless or faint sweet odor
Odor Threshold: Not determined
pH: 5.5 – 7.5 (in 10% water solution)
Melting Point: 103 – 105°C
Boiling Point: Not applicable (decomposes before boiling)
Flash Point: Not determined
Evaporation Rate: Not applicable
Flammability: Not flammable as a solid, but combustible when dust is dispersed in air
Vapor Pressure: Negligible
Vapor Density: Not available
Relative Density: 1.6–1.8 (water = 1)
Solubility: Highly soluble in water (approx. 4 g/mL at 25°C)
Partition Coefficient (n-octanol/water): Not available
Auto-ignition Temperature: Above 400°C
Decomposition Temperature: Above 130°C
Viscosity: Not applicable
Stability: Stable in normal storage and handling conditions
Reactivity: No hazardous reactions expected under standard conditions
Conditions to Avoid: Strong heat, open flame, accumulation of dust in air
Incompatible Materials: Strong oxidizing agents
Hazardous Decomposition Products: Produces carbon oxides and possibly irritating fumes if burned or overheated
Acute Toxicity: Low oral toxicity; LD50 (rat) >15,000 mg/kg
Chronic Effects: Long-term consumption of large quantities may contribute to obesity or metabolic issues, but not toxicity in the traditional sense
Skin Corrosion/Irritation: Not expected to be irritating
Serious Eye Damage/Irritation: May cause mild, reversible irritation on contact
Respiratory Sensitization: Not classified as a sensitizer
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, OSHA
Mutagenicity: No studies indicating genotoxic potential
Reproductive Toxicity: Not toxic for reproduction at normal intake levels
Other Information: Most reported effects relate to excessive nutritional intake rather than direct chemical hazards
Ecotoxicity: Not expected to be hazardous to aquatic or terrestrial life at realistic concentrations
Mobility in Soil: High solubility in water; can be quickly diluted and utilized by microorganisms
Persistence and Degradability: Biodegradable under environmental conditions
Bioaccumulation Potential: Not expected to bioaccumulate
Other Adverse Effects: No known significant environmental hazards or effects under standard use and disposal
Waste Disposal Methods: Dispose of in accordance with local, regional, and national regulations
Contaminated Packaging: Clean packaging thoroughly before recycling or disposal. Rinse containers before discarding
Environmental Precautions: Avoid release to surface water, although rapid degradation and low toxicity reduce risk
UN Number: Not regulated
UN Proper Shipping Name: Not regulated
Transport Hazard Class: Not hazardous for transport
Packing Group: Not applicable
Environmental Hazards: Not a marine pollutant
Special Precautions for User: Keep containers dry and intact during transport. Prevent moisture ingress. Avoid dust emission
Safety, Health, and Environmental Regulations: Food-grade fructose is covered by food safety and chemical safety standards in many regions, including the US FDA and European Food Safety Authority. Not listed as hazardous by major chemical regulatory agencies. Not listed under CERCLA, SARA Title III, or California Prop 65
Workplace Regulations: General workplace dust exposure limits apply
Labeling Requirements: Follow specific local food labeling laws if handled for food usage
Other Information: Consistent with good manufacturing practice. Subject to periodic review and updates by regulatory authorities depending on new scientific findings
